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Two of his papers appeared in and in the Journal de Physique.
In the first, he described concepts of viscosity and springiness that he sought to measure; he also dealt with fluids t h a t showed a yield point, such as weak gelatine gels.
He found t h a t the material relaxed after a step strain, and he tried to use Maxwell's ideas to describe what he saw. In his second paper, Schwedoff concentrated on viscosity. He concluded: " the viscosity is not constant, as one usually supposes: it varies with the speed of shearing". Since he was dealing with gel materials t h a t had a yield stress, 1Maurice Marie Alfred Couette was born in in Tours, France, the only son of a cloth merchant. In , he obtained a bachelor's degree in mathematics from the Faculty of Sciences in Poitiers.
He then enrolled in the newly opened Free Faculty of Sciences in Angers and, in , he received a degree in physics.
After completing one year's voluntary military service, Couette settled in Paris. From , he studied at the Physical Research Laboratory at the Sorbonne, completing his doctoral thesis on "Studies in liquid friction" in In , at the invitation of the Chancellor, Couette returned to the Catholic University of Angers, where he was to spend the next 43 years as Professor of Physical Sciences.
He gave up university teaching in and died ten years later. A full account of Couette's life and scientific achievements is provided by Piau et al We note that J G Butcher invented the terms "elastico-viscous" and "elastico-plastico-viscous", of which 2. The paper of Schwedoff was the forerunner to a multitude of papers on variable viscosity effects in a plethora of materials which were to occupy much of the literature of the first half of the 20th century e.
Hatschek According to Scott Blair , there was a tendency to label all anomalous behaviour as manifestations of 'plasticity', with no clear idea as to what that meant. In , Bingham published an important book entitled "Fluidity and Plasticity".
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It contained a m a m m o t h 82 page bibliography and provided a great deal of information on measurements for various systems, including gel-like materials with a yield stress. It also included an important discussion on 'wall-slip' in viscometers. Strangely, the book does not have a very lengthy discussion on variable-viscosity systems, which probably reflects the mood at the time of writing. This mood had to change, and it did so as a result of rheometrical experiments on a multitude of different materials.
So, by , Scott Blair, in the March issue of 'British Plastics', was able to report that "Rheological methods are in practice applied to an enormous variety of materials.
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Among the more obvious applications are the following: metals elastic and plastic properties , oils, paints and varnishes, bitumens, tars and pitch, gums, inks and starches, flours for bread and biscuit making, cheese, butter, cream and milk, tooth pastes, soaps and toilet creams, ceramic clays, dyestuffs and fibres of all kinds In order to classify the plethora of possibilities in a simple way, the British Rheologists Club published a working chart on rheological behaviour Nature , , p and invited further comments.
References to many of the more relevant contributions to the expanding literature are provided in the books by Houwink , Scott Blair and PhilippotF The book is an important source of reference on the state of colloidal rheology in the early s. We note that the often misunderstood term 'thixotropy', which we discuss in Chapter 7, 2Wladimir Philippoff was born in Peterhof, Russia in and moved to Germany in , receiving his Dr Eng Elec Eng degree in From he worked at the Kaiser Wilhelm Institute of Chemistry on dynamic testing in viscoelasticity.
He was awarded the Bingham medal in Fig 2.
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With the increasing interest in fluid rheology came the need to describe nonlinear fluids in an appropriate manner and a large number of empirical models describing the observed shear stress-shear rate behaviour were invented. This was essentially a curvefitting exercise, and, to be attractive, the models had to contain as few constants as possible.
Most notable amongst the growing list of available models were the Bingham model, the Ostwald -de Waele power-law model, the Herschel-Bulkley model and the Ellis and Williamson models see Houwink , Tanner These are still important today in giving a compact, manageable description of shearing flow.
One could say that if variable viscosity and linear viscoelasticity were the sum total of rheology, then it had all been done by The empirical shear stress-shear rate models were used to derive the relevant flow rate-pressure drop relationships for capillary flow, and these could then be compared with experiment. However, it was soon realized that a procedure was needed to solve the important inverse problem, i. This question was successfully addressed by W e i s s e n b e r g , the provenance of the solution being unexpected, since, at the time , Weissenberg was working at the Berlin crystallographic laboratory of R O Herzog at the Kaiser-Wilhelm Institut fiir Faserstoffchemie Berlin-Dahlem, which was not primarily interested in fluid mechanics.
Weissenberg's interest in these matters can be traced to a paper with Herzog entitled "On the thermal, mechanical and x-ray analysis of swelling" which was published in Kolloid-Zeitschrift.
It is a remarkably wide-ranging paper and sets out a programme of research on the relations of material and molecular structures to thermal and mechanical properties. Whilst this was clearly only a preliminary statement of a vast programme of work, it was recognized that material behaviour might be described as an interplay of kinetic, thermal and elastic energy, and a triangular diagram with vertices labelled with these three forms of energy was displayed.
In a surprising switch from this very general scene to a particular problem, on their p, the first general analysis of the inverse capillary flow begins.
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Please enter recipient e-mail address es. Your request to send this item has been completed. What do you think became of Ting Li and Ong?By common consent, Maxwell was somewhat diffident, a man of quiet disposition, unassuming, devoid of any trace of pomposity, but of great warmth and sure character.
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The theme is easy to use with bundled visual page and portfolio builders. We now need to address the beginnings of serious experimental fluid theology.
The Principia contains Newton's famous hypothesis about the response of fluids to a steady shearing motion, which assured his place in our History.